dc.contributor.author |
Revenco, Mihail |
|
dc.contributor.author |
Martin, Mariana |
|
dc.contributor.author |
Dayyih, Waell Abu |
|
dc.date.accessioned |
2018-03-27T12:06:20Z |
|
dc.date.available |
2018-03-27T12:06:20Z |
|
dc.date.issued |
2010 |
|
dc.identifier.citation |
REVENCO, M. , MARTIN. M. et al. Thiocyanate ion-selective pvc membrane electrode. In: Cemistry Journal of Moldova. 2010, nr.1, pp. 73-77. ISSN1857-1727. |
en |
dc.identifier.issn |
1857-1727 |
|
dc.identifier.uri |
http://dspace.usm.md:8080/xmlui/handle/123456789/1724 |
|
dc.description.abstract |
A potentiometric selective sensor based on trinuclear chromium(III) complex as a novel ionophore for the thiocyanate-selective electrode is reported. The sensor displays a near Nernstian slope of 57 ± 2 mV per decade, over a wide pH range 3 - 11. The working concentration range of the electrode is 1.10-5 – 1.10-1 mol/L with a detection limit of 5.
10-6 mol/L. The sensor has a response time of 20 s and can be used for at least 6 months without any considerable fluctuation of the potential. The selectivity coeffi cients determined at using the fi xed interference method indicate a good discriminating ability towards other anions. The prepared sensor was applied as an indicator electrode in the
titration of thiocyanate with Ag+. |
en |
dc.language.iso |
en |
en |
dc.publisher |
Academia de Știinițe a Moldovei |
en |
dc.subject |
thiocyanate |
en |
dc.subject |
potentiometric sensor |
en |
dc.subject |
titration |
en |
dc.title |
THIOCYANATE ION-SELECTIVE PVC MEMBRANE ELECTRODE |
en |
dc.type |
Article |
en |