THIOCYANATE ION-SELECTIVE PVC MEMBRANE ELECTRODE

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dc.contributor.author Revenco, Mihail
dc.contributor.author Martin, Mariana
dc.contributor.author Dayyih, Waell Abu
dc.date.accessioned 2018-03-27T12:06:20Z
dc.date.available 2018-03-27T12:06:20Z
dc.date.issued 2010
dc.identifier.citation REVENCO, M. , MARTIN. M. et al. Thiocyanate ion-selective pvc membrane electrode. In: Cemistry Journal of Moldova. 2010, nr.1, pp. 73-77. ISSN1857-1727. en
dc.identifier.issn 1857-1727
dc.identifier.uri http://dspace.usm.md:8080/xmlui/handle/123456789/1724
dc.description.abstract A potentiometric selective sensor based on trinuclear chromium(III) complex as a novel ionophore for the thiocyanate-selective electrode is reported. The sensor displays a near Nernstian slope of 57 ± 2 mV per decade, over a wide pH range 3 - 11. The working concentration range of the electrode is 1.10-5 – 1.10-1 mol/L with a detection limit of 5. 10-6 mol/L. The sensor has a response time of 20 s and can be used for at least 6 months without any considerable fluctuation of the potential. The selectivity coeffi cients determined at using the fi xed interference method indicate a good discriminating ability towards other anions. The prepared sensor was applied as an indicator electrode in the titration of thiocyanate with Ag+. en
dc.language.iso en en
dc.publisher Academia de Știinițe a Moldovei en
dc.subject thiocyanate en
dc.subject potentiometric sensor en
dc.subject titration en
dc.title THIOCYANATE ION-SELECTIVE PVC MEMBRANE ELECTRODE en
dc.type Article en


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